| CAS No.: | 9049-71-2 |
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| Formula: | Polyol |
| EINECS: | No |
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| Section 1: Chemical Product and Company Identification 1 |
| Product Name: Blended Polyol : Chemical Family: Polyether Polyol : Trade Name: Polyol : Product Number: : CAS Number: Proprietary CAS : Application: Raw material for producing insulation foam : |
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| Section 2: Composition and Information on Ingredients 2 |
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| No. | Ingredient Name | CAS No CAS |
Weight | ||
| I 1 |
Polyol | 9049-71-2 9049-71-2 |
97.5%min 97.5% |
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| II 2 |
Water | 7732-18-5 7732-18-5 |
2.5%max 2.5% |
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| Section 3: Hazards Identification 3 |
| Emergency Overview Color: Light yellow to red brown : Physical State: Liquid : Odor: Sweet : Hazards of product: May be harmful if swallowed. : , Potential Health Effects Eye Contact: May cause slight temporary eye irritation. Corneal injury is unlikely. : ,. Skin Contact : Essentially nonirritating to skin. Material may be handled at elevated temperatures; contact with heated material may cause thermal burns. :., . Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. : , Inhalation: At room temperature, exposure to vapor is minimal due to low volatility; single exposure is not likely to be hazardous . Vapor from heated material or mist may cause respiratory irritation. :,; .. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. :., |
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| Section 4: First Aid Measures 4 |
| Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist. :.,1-2, ,.,, . Skin Contact: Wash skin with plenty of water. :. Inhalation: Move person to fresh air; if effects occur, consult a physician. :,,. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. :,.,. Notes to Physician: If burn is present, treat as any thermal burn, after decontamination. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. :,,. .. |
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| Personal Protection | G |
| Section 5: Fire and Explosion Data 5 |
| Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective. :.... . () . () ,. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. :,,. . .. ., . . Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance. :, ( ,,,) . ,. Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation. :. Hazardous Combustion Products: Combustion products may include and are not limited to: Carbon monoxidee. Carbon dioxide. Nitrogen oxides. :,,. |
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| Section 6: Accidental Release Measures 6 |
| Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional information. :., ., .13. Personal Precautions: Isolate area. Refer to Section 7, Handling, for additional precautionary measures. Keep unnecessary and unprotected personnel from entering the area. Spilled material may cause a slipping hazard. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. :,7. .,8 . Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. :,,,. 12. |
| Section 7: Handling and Storage 7 |
| Handling General Handling: Do not swallow. Wash thoroughly after handling. Product shipped/handled hot can cause thermal burns. :,./ . Other Precautions: Spills of these organic materials on hot fibrous insulations may lead to lowering of the auto ignition temperatures possibly resulting in spontaneous combustion :, |
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| . Storage Store in the following material(s): Carbon steel. Stainless steel. Polypropylene. Polyethylene-lined container. Teflonn. Glass-lined container. Aluminum. Plasite 3066 lined container. Plasite 3070 lined container. 316 stainless steel. :,,,,, ,,3066,2070316 Shelf life: Use within 6 Months :6 |
| Section 8: Exposure Controls/Personal Protection 8 |
| Exposure Limits None established Personal Protection Eye/Face Protection: Use safety glasses. /: Skin Protection: No precautions other than clean body-covering clothing should be needed. When handling hot material, protect skin from thermal burns. Selection of specific items will depend on the operation. :,,. . Hand protection: Chemical protective gloves should not be needed when handling this material. Consistent with general hygienic practice for any material, skin contact should be minimized. Use gloves with insulation for thermal protection, when needed. :,. ,.. Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions, no respiratory protection should be needed; however, if material is heated |
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| or sprayed, use an approved air-purifying respirator. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter. :,. ,,, ,., ,,,. . Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating. :., .. Engineering Controls Ventilation: Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations. :, . ,., . |
| Section 9: Physical and Chemical Properties 9 |
| Physical State Liquid Color Light yellow to red brown Odor Sweet Flash Point - Closed Cup > 177 °C (> 351 °F) ASTM D93 - >177°C (351°F) D93 Flammable Limits In Air Lower: No test data available Upper: No test data available : : |
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| Autoignition Temperature: No test data available : Vapor Pressure Literature negligible at ambient temperature : Boiling Point (760 mmHg) Literature decomposes prior to boiling. (760mmHg) : Vapor Density (air = 1) > 1 Literature (=1) > 1 Specific Gravity (H2O = 1) > 1.00 Literature (=1) > 1 Freezing Point No test data available Melting Point Not applicable Solubility in Water (by weight) () Literature soluble to slightly soluble at room temperature pH > 7 - < 12.5 Estimated PH >7 -< 12.5 Kinematic Viscosity No test data available : |
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| Section 10: Stability and Reactivity Data 10 |
| Stability/Instability / Stable under recommended storage conditions. See Storage, Section 7. ,7. Conditions to Avoid: Product can oxidize at elevated temperatures. Generation of gas during decomposition can cause pressure in closed systems. :,. . Incompatible Materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates generates heat. :,,. . Hazardous Polymerization Will not occur by itself Thermal Decomposition Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Carbon dioxide. Alcohols. Ethers. Hydrocarbons. Ketones. Polymer fragments. ,.:,, ,, |
| Section 11: Toxicological Information |
| Acute Toxicity Ingestion Typical for this family of materials. Estimated LD50, Rat 1,000 - 2,000 mg/kg |
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| :,,1,000-2000mg/kg Skin Absorption Typical for this family of materials. Estimated LD50, Rabbit > 2,000 mg/kg :,>2,000mg/kg Repeated Dose Toxicity Based on available data, repeated exposures are not anticipated to cause significant adverse effects. ,. |
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| Section 12: Ecological Information |
| CHEMICAL FATE Movement & Partitioning & Based on information for a similar material: Bioconcentration potential is low (BCF less than 100 or log Pow less than 3) : (BCF100logPow<3) Persistence and Degradability Based on information for a similar material: Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions. :, , . ECOTOXICITY Based on information for a similar material: Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 > 100 mg/L in the most sensitive species tested). : (, />100mg/L) ,. |
| Section 13: Disposal Considerations |
| DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. HBL HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF |
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| PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Recycler,Reclaimer,Incinerator or other thermal destruction device. For additional information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section 10 Regulatory Information, MSDS Section 15 As a service to its customers, HBL can provide names of information resources to help identify waste management companies and other facilities which recycle, reprocess or manage chemicals or plastics, and that manage used drums. Telephone HBL's Customer Information Group at 0086-025-58390063 or 0086-025-57350966 for further details. ,, ,MSDS:. ,,, .,:,MSDS7 ,10,15., ,,. 0086-025-583900630086-025-57350966. |
| Section 14: Transport Information 14 |
| DOT Non-Bulk NOT REGULATED DOT Bulk NOT REGULATED IMDG NOT REGULATED ICAO/IATA / NOT REGULATED |
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This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. /. . ,. |
| Section 15: Regulatory Information 15 |
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| National Regulations (China) () Unlisted Substance: No. : State Component Listing: : State Comment: None identified. : National Regulations (China) () Chinese DSL Registration: No : OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). : (29CFR1910.1200) , EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. : Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 1986III (1986) 311 |
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| 312 Immediate (Acute) Health Hazard () Delayed (Chronic) Health Hazard |
No No |
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| () Fire Hazard No Reactive Hazard No . HMIS (U.S.A.): () Health Hazard: 1 1 Fire Hazard: 1 1 Reactivity: 0 0 Personal Protection: g g National Fire Protection Association (U.S.A.): Health: 1 1 Flammability: 1 1 Reactivity: 0 0 Specific hazard: none Protective Equipment: Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Safety glasses. |
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| Section 16: Other Information 16 |
| Disclaimer: Supplier gives no warranty of merchant ability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser will make his own test to determine the quality and suitability of the product. Supplier expressly disclaims any all liability for incidental and /or consequential property damage arising out of the use of this product .No information provided shall be deemed safety data sheet before handling pro |
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